TY - JOUR AB - A recently developed novel intense rare-gas excimer vacuum ultraviolet (VUV) light source, the electron beam-pumped excimer lamp (EBEL), has been applied to the soft single-photon ionization (SPI) of organic molecules in a compact orthogonal acceleration time-of-flight mass spectrometer (oaTOFMS). The SPI-oaTOFMS system was applied to the on-line monitoring of tobacco smoke. With this setup, it was possible to analyze the composition of individual puffs of cigarette smoke. Furthermore, a gas chromatograph (GC) was coupled to the EBEL SPIoaTOFMS system. Soft photo-ionization represents an additional separation dimension. By combination of the gas chromatographic and the soft-ionization mass spectroscopic separation dimensions, a truly multidimensional comprehensive analytical method could be derived. AU - Zimmermann, R. AU - Mühlberger, F. AU - Fuhrer, K.* AU - Gonin, M.* AU - Welthagen, W. C1 - 3268 C2 - 25374 SP - 24-31 TI - An ultracompact photo-ionization time-of-flight mass spectrometer with a novel vacuum ultraviolet light source for on-line detection of organic trace compounds and as a detector for gas chromatography. JO - J. Mater. Cycles Waste Manag. VL - 10 IS - 1 PB - Springer PY - 2008 SN - 1438-4957 ER -