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Open Access Green möglich sobald Postprint bei der ZB eingereicht worden ist.
Element speciation definitions, analytical methodology and some examples.
Ecotoxicol. Environ. Saf. 56, 122-139 (2003)
This paper gives definitions related to element speciation and the reasons for the need for speciation. The problems focused on, involve sampling, sample preparation and storage, as well as changes in species information that occur during the use of various separation technologies. However, the potential and advantages of the separation methods in element speciation are also discussed. In addition, problems arising during element detection that are attributable to analytes or mobile-phase composition are outlined, as well as the pronounced advantages of detection by inductively coupled plasma–mass spectrometry (ICP-MS). The combination of the various separation systems with element- or molecule-specific detectors creates problems especially in element speciation. These difficulties are described along with recent developments for overcoming them or for improving their coupling efficiency. Finally, several elements for which the issue of speciation is important are discussed, with examples from some recent publications on arsenic, selenium and iodine speciation.
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Publikationstyp
Artikel: Journalartikel
Dokumenttyp
Wissenschaftlicher Artikel
Schlagwörter
Speciation; Hyphenated (coupled) techniques; Interfacing; Element selective detection; Molecule selective detection; Quality control
ISSN (print) / ISBN
0147-6513
e-ISSN
0147-6513
Zeitschrift
Ecotoxicology and Environmental Safety
Quellenangaben
Band: 56,
Heft: 1,
Seiten: 122-139
Verlag
Elsevier
Nichtpatentliteratur
Publikationen
Begutachtungsstatus
Peer reviewed
Institut(e)
Institute of Ecological Chemistry (IOEC)