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Main products and kinetics of the thermal degradation of polyamids.
Chemosphere 42, 601-607 (2001)
The thermal degradation of the polyamides (PA) 6, 12, 66 and 612 was investigated by means of thermal analysis/mass spectrometry (TA-MS) and pyrolysis in a german standard oven. Sample masses were about 20 and 40 mg. The heating rates used in the dynamic studies were 1, 5 and 10 K min(-1). Both air and nitrogen atmospheres were utilized. The kinetic parameters were calculated from the TA-MS measurements and the main decomposition products were registered online. The evolved products from the pyrolysis oven were captured and analyzed off-line by GC/MS.
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Publikationstyp
Artikel: Journalartikel
Dokumenttyp
Wissenschaftlicher Artikel
Schlagwörter
Thermal decomposition; Pyrolysis; Dynamic measurements; TA-MS
ISSN (print) / ISBN
0045-6535
e-ISSN
1879-1298
Zeitschrift
Chemosphere
Quellenangaben
Band: 42 ,
Heft: 5,
Seiten: 601-607
Verlag
Elsevier
Verlagsort
Kidlington, Oxford
Begutachtungsstatus
Peer reviewed
Institut(e)
Institute of Ecological Chemistry (IOEC)