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Open Access Green möglich sobald Postprint bei der ZB eingereicht worden ist.
Prediction of Soil Adsorption Coefficients from Retention Parameters on Three Reversed-Phase Liquid Chromatographic Colums.
Anal. Chem. 74, 655-660 (2002)
Reversed-phase high-performance liquid chromatographic (RP-HPLC) retention parameters, which are determined by the intermolecular interactions in retention process, can be considered as the chemical molecular descriptors in linear free energy relationships (LFERs). On the basis of the characterization and comparison of octadecyl-bonded silica gel (ODS), cyano-bonded silica gel (CN), and phenyl-bonded silica gel (Ph) columns with linear solvation energy relationships (LSERs), a new multiple linear regression model using RP-HPLC retention parameters on ODS and CN columns as variables for estimation of soil adsorption coefficients was developed. It was tested on a set of reference substances from various chemical classes. The results showed that the multicolumn method was more promising than a single-column method was for the estimation of soil adsorption coefficients. The accuracy of the suggested model is identical with that of LSERs.
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Publikationstyp
Artikel: Journalartikel
Dokumenttyp
Wissenschaftlicher Artikel
Schlagwörter
HPLC STATIONARY PHASES; ORGANIC PARTITION-COEFFICIENTS; K-OC; RP-HPLC; AROMATIC-HYDROCARBONS; 8 PESTICIDES; WATER; KOC; SORPTION; DEISOPROPYLATRAZINE
ISSN (print) / ISBN
0003-2700
e-ISSN
1520-6882
Zeitschrift
Analytical Chemistry
Quellenangaben
Band: 74,
Heft: 3,
Seiten: 655-660
Verlag
American Chemical Society (ACS)
Nichtpatentliteratur
Publikationen
Begutachtungsstatus
Peer reviewed
Institut(e)
Institute of Ecological Chemistry (IOEC)