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Thevenot, M.* ; Dousset, S.* ; Hertkorn, N. ; Schmitt-Kopplin, P. ; Andreux, F.*

Interactions of diuron with dissolved organic matter from organic amendments.

Sci. Total Environ. 407, 4297-4302 (2009)
DOI PMC
Open Access Green möglich sobald Postprint bei der ZB eingereicht worden ist.
Diuron is frequently detected in some drinking water reservoirs under the Burgundy vineyards, where organic amendments are applied. The environmental effect of these amendments on pesticide transport is ambiguous: on the one hand it could enhance their retention by increasing soil organic carbon content; on the other hand, dissolved organic matter (DOM) could facilitate their transport. Elutions were performed using columns packed with glass beads in order to investigate DOM-diuron interactions, and the possible co-transport of diuron and DOM. Four organic amendments (A, B, C and D) were tested; C and D were sampled at fresh (F) and mature (M) stages. An increase in diuron leaching was observed only for A and D-F amendments (up to 16% compared to the DOM-free blank samples), suggesting a DOM effect on diuron transport. These results could be explained by the higher DOM leaching for A and D-F compared to B, C-F, C-M and D-M increasing diuron-DOM interactions. These interactions seem to be related to the aromatic and aliphatic content of the DOM, determining formation of hydrogen and non-covalent bonds. The degree of organic matter maturity does not seem to have any effect with amendment C, while a reduction in diuron leaching is observed between DF and D-M. After equilibrium dialysis measurement of diuron-DOM complexes, it appeared that less than 3% of the diuron applied corresponded to complexes with a molecular weight > 1000 Da. Complexes < 1000 Da could also take part in this facilitated transport.
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Publikationstyp Artikel: Journalartikel
Dokumenttyp Wissenschaftlicher Artikel
Schlagwörter Pesticide; Dissolved organic matter; Facilitated transportS.; Diuron; compost maturity; sorption; soil; carbon; herbicideS.; spectroscopy; napropamide; chemistry; strength; simazine
ISSN (print) / ISBN 0048-9697
e-ISSN 1879-1026
Zeitschrift Science of the Total Environment, The
Quellenangaben Band: 407, Heft: 14, Seiten: 4297-4302 Artikelnummer: , Supplement: ,
Verlag Elsevier
Begutachtungsstatus Peer reviewed
Institut(e) Institute of Ecological Chemistry (IOEC)