Open Access Green möglich sobald Postprint bei der ZB eingereicht worden ist.
On-line measurement of chlorobenzene in waste incineration flue gas as a surrogate for the emission of polychlorinated dibenzo-p-dioxins/furans (I-TEQ) using mobile resonance laser ionization time-of-flight mass spectrometry.
Rapid Commun. Mass Spectrom. 13, 307-314 (1999)
Mobile resonance-enhanced multiphoton ionization time-of-flight mass spectrometry (REMPI-TOFMS) was applied for on-line detection of surrogates for polychlorinated dibenzo-p-dioxins/furans (PCDD/F) in the flue gas of an industrial hazardous waste incineration plant (thermal power: 22 MW). Conventional gas chromatography/mass spectrometry (GC/MS) measurements have been performed to establish an indicator relation between the best suited surrogate (monochlorobenzene) and the PCDD/F concentration in the flue gas (measured in international toxicity equivalents, I-TEQ). The indicator relation allows the estimation of the actual PCDD/F emission from the on-line registered MCBz signal. Furthermore, several other aromatic components have been measured on-line. During transient instabilities of the combustion conditions, e.g. due to barrel uptake, highly dynamic changes in the emission profiles of substituted benzenes and polycyclic aromatic hydrocarbons (PAH) were observed.
Impact Factor
Scopus SNIP
0.000
0.000
Anmerkungen
Besondere Publikation
Auf Hompepage verbergern
Publikationstyp
Artikel: Journalartikel
Dokumenttyp
Wissenschaftlicher Artikel
Sprache
englisch
Veröffentlichungsjahr
1999
HGF-Berichtsjahr
0
ISSN (print) / ISBN
0951-4198
e-ISSN
1097-0231
Zeitschrift
Rapid Communications in Mass Spectrometry
Quellenangaben
Band: 13,
Seiten: 307-314
Verlag
Wiley
Begutachtungsstatus
Peer reviewed
Institut(e)
Institute of Ecological Chemistry (IOEC)
Erfassungsdatum
1999-12-31