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Lalah, J.O.* ; Schramm, K.-W. ; Lenoir, D. ; Henkelmann, B. ; Hertkorn, N. ; Matuschek, G. ; Kettrup, A. ; Günther, K.*

Regioselective Synthesis of a Branched Isomer of Nonylphenol, 4-(3',6'-Dimethyl-3'-heptyl)phenol and Determination of its Important Environmental Properties.

Chem. Eur. J. 7, 4790-4795 (2001)
DOI
Open Access Green möglich sobald Postprint bei der ZB eingereicht worden ist.
A method for the synthesis of a pure nonylphenol isomer, 4-(3′,6′-dimethyl-3′-heptyl)phenol, by Friedel–Crafts reaction between anisole and 3-bromo-3,6-dimethylheptane that gives a 47.3 % overall yield is reported. The reactions were followed by GC-MS, and the chemical structures are in agreement with the NMR and IR spectra. The log Kow value for this compound, its water solubility, vapor pressure, and Henry's Law constant were also determined. These physicochemical properties were required for prediction of the compound's behavior in aquatic ecosystems.
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Publikationstyp Artikel: Journalartikel
Dokumenttyp Wissenschaftlicher Artikel
Korrespondenzautor
Schlagwörter environmental chemistry Friedel-Ctafts alkylation nonylphenol isomer synthesis design
ISSN (print) / ISBN 0947-6539
e-ISSN 1521-3765
Quellenangaben Band: 7, Heft: 22, Seiten: 4790-4795 Artikelnummer: , Supplement: ,
Verlag Wiley
Nichtpatentliteratur Publikationen
Begutachtungsstatus Peer reviewed
Institut(e) Institute of Ecological Chemistry (IOEC)