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Open Access Green möglich sobald Postprint bei der ZB eingereicht worden ist.
Regioselective Synthesis of a Branched Isomer of Nonylphenol, 4-(3',6'-Dimethyl-3'-heptyl)phenol and Determination of its Important Environmental Properties.
Chem. Eur. J. 7, 4790-4795 (2001)
A method for the synthesis of a pure nonylphenol isomer, 4-(3′,6′-dimethyl-3′-heptyl)phenol, by Friedel–Crafts reaction between anisole and 3-bromo-3,6-dimethylheptane that gives a 47.3 % overall yield is reported. The reactions were followed by GC-MS, and the chemical structures are in agreement with the NMR and IR spectra. The log Kow value for this compound, its water solubility, vapor pressure, and Henry's Law constant were also determined. These physicochemical properties were required for prediction of the compound's behavior in aquatic ecosystems.
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Publikationstyp
Artikel: Journalartikel
Dokumenttyp
Wissenschaftlicher Artikel
Schlagwörter
environmental chemistry Friedel-Ctafts alkylation nonylphenol isomer synthesis design
ISSN (print) / ISBN
0947-6539
e-ISSN
1521-3765
Zeitschrift
Chemistry - A European Journal
Quellenangaben
Band: 7,
Heft: 22,
Seiten: 4790-4795
Verlag
Wiley
Nichtpatentliteratur
Publikationen
Begutachtungsstatus
Peer reviewed
Institut(e)
Institute of Ecological Chemistry (IOEC)