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Oxygen isotope exchange between sulphate and water during bacterial reduction of sulphate.
Chem. Geol. 79, 99-105 (1989)
The bacterial reduction of sulphate is accompanied by oxygen isotope exchange reactions. The mechanisms were not investigated in detail but it is suggested that the formation of sulphate-enzyme complexes as intermediary reaction products are facilitating the exchange of 18O between water and sulphate. Under the experimental conditions the observed fractionation factor is close to 25‰ at 30°C and approaches 27‰ at 17°C. Extrapolated values from a field study indicate a difference of ∼ 29‰ at ∼ 5°C.
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Publikationstyp
Artikel: Journalartikel
Dokumenttyp
Wissenschaftlicher Artikel
ISSN (print) / ISBN
0009-2541
e-ISSN
1872-6836
Zeitschrift
Chemical Geology
Quellenangaben
Band: 79,
Heft: 2,
Seiten: 99-105
Verlag
Elsevier
Begutachtungsstatus
Peer reviewed
Institut(e)
Institut für Hydrologie