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Synthese 14C-markierter Umweltchemikalen.
Synthesis of 14 C labeled environment contaminants.
J. Labelled Comp. Radiopharm. 14, 197-204 (1978)
Upon the reaction of benzene-14C via nitrobenzene-14C and aniline-14C, some 14C-labelled environmental contaminants were were synthesized. By chlorination of aniline-14C and acetanilide-14C the authors prepared chloroanilines-14C. Gomberg-Bachmann or Cadogan reaction of diazotated chloroanilines-14C with different chlorobenzenes gave di, tri- and pentachlorobiphenyls-14C. By boiling anilinediazonium sulfate-14C the authors prepared phenol-14C, which was chlorinated to give 2,4,6-trichlorophenol-14C. Hexachlorobenzene-14C and pentachloronitrobenzene-14C were prepared by chlorination of nitrobenzene- 14C. Chloralkylene 9-14C was synthesized by Friedel-Crafts alkylation of 2,4'-dichlorobiphenyl-14C with 2-chloropropane.
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Publikationstyp
Sonstiges: Korrektur, Ergänzung
Schlagwörter
Pentachloronitrobenzene; Hexachlorobenzene; Pentachloro
ISSN (print) / ISBN
0362-4803
e-ISSN
1099-1344
Quellenangaben
Band: 14,
Heft: 2,
Seiten: 197-204
Verlag
Wiley
Nichtpatentliteratur
Publikationen
Begutachtungsstatus
Peer reviewed
Institut(e)
Institute of Ecological Chemistry (IOEC)