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Schuhmann, W. ; Josel, H.P. ; Parlar, H.A.

New photosynthesis-like system for the light-induced reduction of water to molecular hydrogen.

Angew. Chem.-Int. Edit. 26, 241-243 (1987)
DOI
Open Access Green möglich sobald Postprint bei der ZB eingereicht worden ist.
Two zinc porphyrinate-modified Pt electrodes form the essential part of a very promising solar energy conversion system in which ultimately water is reduced to hydrogen. The Na//2 salt of ethylenediaminetetraacetic acid is employed as sacrificial electron donor; methyl viologen functions as electron transfer agent and platinized TiO//2 as reduction catalyst. Decisive is that the anode is coated with an n-semiconducting porphyrinate (zinc 5-(4-pyridyl)-10,15,20-tritolylporphyrinate) and the cathode with a p-semiconducting porphyrinate (zinc 5,10,15,20-tetra(4-pyridyl)porphyrinate).
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Publikationstyp Artikel: Journalartikel
Dokumenttyp Wissenschaftlicher Artikel
Korrespondenzautor
ISSN (print) / ISBN 1433-7851
e-ISSN 1521-3773
Zeitschrift Angewandte Chemie - Internationale Edition
Quellenangaben Band: 26, Heft: 3, Seiten: 241-243 Artikelnummer: , Supplement: ,
Verlag Wiley
Verlagsort Weinheim
Nichtpatentliteratur Publikationen
Begutachtungsstatus Peer reviewed
Institut(e) Institute of Ecological Chemistry (IOEC)