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The reaction of sulfite radical anion with nucleic acid components.
Free Radic. Res. 2, 285-288 (1987)
The sulfite radical anion (SO3 -) is the first intermediate in the autoxidation of sulfite to sulfate. Using competition kinetics, its reactivities with the nucleic acid bases and the corresponding nucleosides were investigated. The second order rate constants were found to be rather low, k < 1 × 106dm3mol-1s-1 at pH 7. As a competitor, the carotenoid crocin was used, which was found to be bleached very efficiently by SO3 - (k = 1.0 × 109dm3mol-1S-1).
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Publikationstyp
Artikel: Journalartikel
Dokumenttyp
Wissenschaftlicher Artikel
Schlagwörter
Competition Studies ; Crocin ; Nucleic Acid Bases ; Nucleosides ; Pulse Radiolysis ; Rate Constants ; Sulfite Radical
ISSN (print) / ISBN
1071-5762
e-ISSN
1029-2470
Zeitschrift
Free Radical Research
Quellenangaben
Band: 2,
Heft: 4-6,
Seiten: 285-288
Verlag
Taylor & Francis
Begutachtungsstatus
Peer reviewed
Institut(e)
Institute of Radiation Biology (ISB)