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Gäb, S. ; Turner, W.V.

1,1-Dichloroethyl hydroperoxide and 1,1-dichloroethyl peroxide ion as intermediates in the ozonolysis of 2,3-dichloro-2-butene.

J. Org. Chem. 49, 2711-2714 (1984)
DOI
Open Access Green möglich sobald Postprint bei der ZB eingereicht worden ist.
On the basis of its spectroscopic and chemical properties, an unstable intermediate previously detected in the ozonolysis of trans-2,3-dichloro-2-butene (1) in inert solvents is reformulated as 1,1-dichloroethyl hydroperoxide (5). Ozonolysis of 1 in ethyl formate saturated with anhydrous HCl leads to high yields of this intermediate. 1,1-Dichloroethyl peroxide ion (10), rather than 5, is believed to be the precursor of acetyl 1,1-dichloroethyl peroxide (8), which is produced in higher yield on ozonolysis of 1 in the presence of tetraalkylammonium chloride.
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Publikationstyp Artikel: Journalartikel
Dokumenttyp Wissenschaftlicher Artikel
Korrespondenzautor
ISSN (print) / ISBN 0022-3263
e-ISSN 1520-6904
Zeitschrift Journal of Organic Chemistry, The
Quellenangaben Band: 49, Heft: 15, Seiten: 2711-2714 Artikelnummer: , Supplement: ,
Verlag American Chemical Society (ACS)
Nichtpatentliteratur Publikationen
Begutachtungsstatus Peer reviewed
Institut(e) Institute of Ecological Chemistry (IOEC)