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    Evolved gas analysis (EGA) in TG and DSC with single photon ionisation mass spectrometry (SPI-MS: Molecular organic signatures from pyrolysis of soft and hard wood, coal, crude oil and ABS polymer.
        
        J. Therm. Anal. Calorim. 96, 795-804 (2009)
    
    
    
				A combined thermogravimetry/differential scanning calorimetry device (TG/DSC) was coupled to single photon ionisation mass spectrometry (SPI-MS) for evolved gas analysis (EGA). Single photon ionisation (SPI) was performed with a new type of VUV light source, the so called electron beam pumped rare gas excimer lamp (EBEL). SPI does not fragment molecules upon the ionisation process. Thus the molecular mass signature of the evolving gases from thermal composition of carbonaceous material can be directly on-line recorded. In this work the thermo-analytical data and the SPI-MS information on the released organics is presented and discussed for various samples. Namely biomass (soft and hard wood), fossil fuel (crude oil and coal) as well as a complex polymer (ABS) are investigated. The general potential of hyphenating thermal analysis and soft photo ionisation mass spectrometry (EBEL-SPI-MS) for fundamental and applied research and material analysis is discussed.
			
			
		Impact Factor
					Scopus SNIP
					Web of Science
Times Cited
					Times Cited
Scopus
Cited By
					
					Cited By
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				1.630
					1.073
					48
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        Publikationstyp
        Artikel: Journalartikel
    
 
    
        Dokumenttyp
        Wissenschaftlicher Artikel
    
 
     
    
    
        Schlagwörter
        TG/MS; Photo-ionisation; Wood; Fossil fuels; electron-impact ionization; enhanced multiphoton ionization; excimer light-source; thermal-degradation; thermogravimetry; mixtures; chromatography; polystyrene; decomposition; components
    
 
     
    
    
        Sprache
        englisch
    
 
    
        Veröffentlichungsjahr
        2009
    
 
     
    
        HGF-Berichtsjahr
        2009
    
 
    
    
        ISSN (print) / ISBN
        1388-6150
    
 
    
        e-ISSN
        1588-2926
    
 
     
     
     
	     
	 
	 
    
        Zeitschrift
        Journal of Thermal Analysis and Calorimetry
    
 
		
    
        Quellenangaben
        
	    Band: 96,  
	    Heft: 3,  
	    Seiten: 795-804 
	    
	    
	
    
 
  
         
        
            Verlag
            Springer
        
 
         
	
         
         
         
         
         
	
         
         
         
    
         
         
         
         
         
         
         
    
        Begutachtungsstatus
        Peer reviewed
    
 
    
        Institut(e)
        Institute of Ecological Chemistry (IOEC)
Cooperation Group Comprehensive Molecular Analytics (CMA)
 
    Cooperation Group Comprehensive Molecular Analytics (CMA)
        POF Topic(s)
        
    
 
    
        Forschungsfeld(er)
        
    
 
    
        PSP-Element(e)
        G-505100-002
    
 
     
     	
    
    
        WOS ID
        000268583900018
    
    
        Scopus ID
        68349090365
    
    
        Erfassungsdatum
        2009-09-03