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Wanczek, K.P.* ; Kanawati, B.

Gas phase ion-molecule reactions of inorganic compounds in FT-ICR-MS.

In: Fundamentals and Applications of Fourier Transform Mass Spectrometry. 2019. 569-591
DOI
Reactions between ions and reactive neutrals in the gas phase at near thermal energy conditions are feasible, provided that means exist to trap ions for a couple of seconds for collisions between ions and reactive neutrals to occur. The ion cyclotron resonance (ICR) technique provides an excellent environment for such gas phase ion-molecule reactions to take place, giving also the opportunity to correlate both reactant and product ions and to determine sum formulae with ultra-high resolution. Moreover, ICR can also enable structure elucidation by several techniques like collision induced dissociation (CID) experiments. Acceleration of some reactive ions can also induce endothermic ion-molecule reactions to occur. The authors give a systematic overview of gas phase ion chemistry of non-metal main group elements, covering a wide spectrum of reactions, as well as their rate constant determinations and thermodynamic ion energetics.
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Publikationstyp Artikel: Sammelbandbeitrag/Buchkapitel
Sprache englisch
Veröffentlichungsjahr 2019
HGF-Berichtsjahr 2019
Bandtitel Fundamentals and Applications of Fourier Transform Mass Spectrometry
Quellenangaben Band: , Heft: , Seiten: 569-591 Artikelnummer: , Supplement: ,
Institut(e) Research Unit BioGeoChemistry and Analytics (BGC)
POF Topic(s) 30202 - Environmental Health
Forschungsfeld(er) Environmental Sciences
PSP-Element(e) G-504800-001
DOI 10.1016/B978-0-12-814013-0.00018-1
Scopus ID 85081541254
Erfassungsdatum 2020-01-20
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