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Identification of polyborate ions in aqueous solution by electrospray ionisation Fourier transform ion cyclotron resonance mass spectrometry.
Eur. J. Mass Spectrom. 16, 237-242 (2010)
Ultra-high-resolution mass spectrometry was used to investigate polyborate species in aqueous solution. The mass spectrum of boric acid revealed clusters of polyborate ions. Constituents with up to 19 B atoms were assigned and 15 species and their relationship were investigated in depth with collision-induced fragmentation. Based on the observed fragments, we proposed herein a potential fragmentation pathway for the observed polyborate molecules.
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Publikationstyp
Artikel: Journalartikel
Dokumenttyp
Wissenschaftlicher Artikel
Schlagwörter
boron; polyborate; borate; boric acid; mass spectrometry; FT-ICR /MS; collusion-induced fragmentation; electrospray ionization
ISSN (print) / ISBN
1469-0667
e-ISSN
1751-6838
Zeitschrift
European Journal of Mass Spectrometry
Quellenangaben
Band: 16,
Heft: 2,
Seiten: 237-242
Verlag
IM Publications
Nichtpatentliteratur
Publikationen
Begutachtungsstatus
Peer reviewed
Institut(e)
Institute of Ecological Chemistry (IOEC)