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Main products and kinetics of the thermal degradation of polyamids.

Chemosphere 42, 601-607 (2001)
DOI PMC
Open Access Gold as soon as Publ. Version/Full Text is submitted to ZB.
The thermal degradation of the polyamides (PA) 6, 12, 66 and 612 was investigated by means of thermal analysis/mass spectrometry (TA-MS) and pyrolysis in a german standard oven. Sample masses were about 20 and 40 mg. The heating rates used in the dynamic studies were 1, 5 and 10 K min(-1). Both air and nitrogen atmospheres were utilized. The kinetic parameters were calculated from the TA-MS measurements and the main decomposition products were registered online. The evolved products from the pyrolysis oven were captured and analyzed off-line by GC/MS.
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Publication type Article: Journal article
Document type Scientific Article
Keywords Thermal decomposition; Pyrolysis; Dynamic measurements; TA-MS
ISSN (print) / ISBN 0045-6535
e-ISSN 1879-1298
Journal Chemosphere
Quellenangaben Volume: 42 , Issue: 5, Pages: 601-607 Article Number: , Supplement: ,
Publisher Elsevier
Publishing Place Kidlington, Oxford
Reviewing status Peer reviewed
Institute(s) Institute of Ecological Chemistry (IOEC)