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Lenoir, D.

The electrophilic substitution of arenes : Is the Pi-complex a key intermediate and what is its nature?

Angew. Chem.-Int. Edit. 42, 854-858 (2003)

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Open Access Green as soon as Postprint is submitted to ZB.

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Aromatic substitution in detail: How does one prove that the intermediate charge-transfer (CT) complex (see scheme, where E=electrophile) is a key intermediate in the electrophilic substitution of arenes, and what is the structure, nature, and significance of this intermediate? On the basis of recent experimental findings these questions and others will be examined.

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Publication type Article: Journal article

Document type Scientific Article

Corresponding Author

Keywords ab initio calculations; arenes; aromatic substitutions; electrophilic additions; reaction mechanisms

ISSN (print) / ISBN 1433-7851

e-ISSN 1521-3773

Journal Angewandte Chemie - Internationale Edition

Quellenangaben Volume: 42, Pages: 854-858

Publisher Wiley

Publishing Place Weinheim

Non-patent literature Publications

Reviewing status Peer reviewed

Institute(s) Institute of Ecological Chemistry (IOEC)