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Open Access Green as soon as Postprint is submitted to ZB.
The electrophilic substitution of arenes : Is the Pi-complex a key intermediate and what is its nature?
Angew. Chem.-Int. Edit. 42, 854-858 (2003)
Aromatic substitution in detail: How does one prove that the intermediate charge-transfer (CT) complex (see scheme, where E=electrophile) is a key intermediate in the electrophilic substitution of arenes, and what is the structure, nature, and significance of this intermediate? On the basis of recent experimental findings these questions and others will be examined.
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Publication type
Article: Journal article
Document type
Scientific Article
Keywords
ab initio calculations; arenes; aromatic substitutions; electrophilic additions; reaction mechanisms
ISSN (print) / ISBN
1433-7851
e-ISSN
1521-3773
Quellenangaben
Volume: 42,
Pages: 854-858
Publisher
Wiley
Publishing Place
Weinheim
Reviewing status
Peer reviewed
Institute(s)
Institute of Ecological Chemistry (IOEC)