PuSH - Publication Server of Helmholtz Zentrum München: Selenium speciation analysis in a sediment using strong anion exchange and reversed phase chromatography coupled plasma-mass spectrometry.

Navigation

Home

Deutsch

Research

Advanced Search

Browse by ...

... Journal

... Publication Type

... Research Data

... Publication Year

Publication overview

Support & Contact

Contact persons

Help

Data protection

Ochsenkühn-Petropoulou, M.* ; Michalke, B. ; Kavouras, D.* ; Schramel, P.

Selenium speciation analysis in a sediment using strong anion exchange and reversed phase chromatography coupled plasma-mass spectrometry.

Anal. Chim. Acta 478, 219-227 (2003)

DOI

Open Access Green as soon as Postprint is submitted to ZB.

Abstract
Metrics
Extra information

An analytical procedure for selenium speciation of analysis of selenourea (SeU), selenoethionine (SeE), selenomethionine (SeM), Se(VI), Se(IV), dimethylselenide (dMeSe) and dimethyldiselenide (dMedSe) was developed, based on two complementary liquid chromatography (LC) techniques coupled with inductively coupled plasma-mass spectrometry (ICP-MS). Specifically, strong anion exchange (SAX) chromatography coupled with ICP-MS was used for the separation and quantification of all the earlier mentioned Se compounds, except for the two methyl selenides, which could be separated and determined by reversed phase chromatography coupled with ICP-MS. This procedure was applied to a soil sample from the warm springs area of Thermopyles (Greece). For leaching the Se species from the soil sample, four extraction methods, using water at ambient temperature, hot water, methanol and 0.5 M HCl, were tested for their efficiency of extracting the different Se species. The speciation results obtained by the LC-ICP-MS methods were compared with those obtained by voltammetric techniques. The determination of total selenium in the sample was achieved by graphite furnace atomic absorption spectrometry, as well as by ICP-atomic emission spectrometry, after suitable digestion of the sediment sample.

Altmetric

Additional Metrics?

[➜Log in]

Edit extra informations Login

Publication type Article: Journal article

Document type Scientific Article

Corresponding Author

Keywords Selenium speciation; Sediments; Strong anion exchange chromatography; Reversed phase chromatography; Graphite furnace atomic absorption spectrometry; Iductively coupled plasma-atomic emission spectrometry; Inductively coupled plasma-mass spectrometry

ISSN (print) / ISBN 0003-2670

e-ISSN 1873-4324

Journal Analytica Chimica Acta

Quellenangaben Volume: 478, Issue: 2, Pages: 219-227

Publisher Elsevier

Non-patent literature Publications

Reviewing status Peer reviewed

Institute(s) Institute of Ecological Chemistry (IOEC)