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Combined utilization of ion mobility and ultra-high-resolution mass spectrometry to identify multiply charged constituents in natural organic matter.
Rapid Commun. Mass Spectrom. 23, 683-688 (2009)
Natural organic matter as complex biogeochemical non-repetitive material was investigated with ion mobility mass spectrometry (IMS) and ultra-high-resolution Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) approaches in order to unravel the existence of multiply charged state constituents. Hereby we describe and assign the potential molecular formulae of these doubly charged species, derived from FTICR-MS, and the existence of these species was confirmed via IMS. The parallel application of these powerful techniques enabled the boundaries of the understanding of natural organic matter to be pushed further.
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Publication type
Article: Journal article
Document type
Scientific Article
Keywords
elemental composition; fulvic-acids; humic substances; ionization; carbon; river; bioavailability; fragmentation; abundance; spectra
ISSN (print) / ISBN
0951-4198
e-ISSN
1097-0231
Quellenangaben
Volume: 23,
Issue: 5,
Pages: 683-688
Publisher
Wiley
Non-patent literature
Publications
Reviewing status
Peer reviewed
Institute(s)
Institute of Ecological Chemistry (IOEC)