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Another look at the photodechlorination of bromodan.
Tetrahedron 45, 3711-3716 (1989)
Contrary to a previous report, there is no solvent-dependent selectivity to either of the double-bond-dechlorinated derivatives when Bromodan is irradiated in hexane or methanol. The 7-dechlorinated derivative formed on photolysis in triethyl amine is debrominated on further irradiation. 13C chemical shifts and long-range CH coupling constants indicate that the structural assignment of the double-bond-dechlorinated isomers must be reversed.
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Publication type
Article: Journal article
Document type
Scientific Article
ISSN (print) / ISBN
0040-4020
e-ISSN
1464-5416
Journal
Tetrahedron
Quellenangaben
Volume: 45,
Issue: 12,
Pages: 3711-3716
Publisher
Elsevier
Non-patent literature
Publications
Reviewing status
Peer reviewed
Institute(s)
Institute of Ecological Chemistry (IOEC)