Contrary to a previous report, there is no solvent-dependent selectivity to either of the double-bond-dechlorinated derivatives when Bromodan is irradiated in hexane or methanol. The 7-dechlorinated derivative formed on photolysis in triethyl amine is debrominated on further irradiation. 13C chemical shifts and long-range CH coupling constants indicate that the structural assignment of the double-bond-dechlorinated isomers must be reversed.