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Another look at the photodechlorination of bromodan.

Tetrahedron 45, 3711-3716 (1989)
DOI
Open Access Green as soon as Postprint is submitted to ZB.
Contrary to a previous report, there is no solvent-dependent selectivity to either of the double-bond-dechlorinated derivatives when Bromodan is irradiated in hexane or methanol. The 7-dechlorinated derivative formed on photolysis in triethyl amine is debrominated on further irradiation. 13C chemical shifts and long-range CH coupling constants indicate that the structural assignment of the double-bond-dechlorinated isomers must be reversed.
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Publication type Article: Journal article
Document type Scientific Article
Corresponding Author
ISSN (print) / ISBN 0040-4020
e-ISSN 1464-5416
Journal Tetrahedron
Quellenangaben Volume: 45, Issue: 12, Pages: 3711-3716 Article Number: , Supplement: ,
Publisher Elsevier
Non-patent literature Publications
Reviewing status Peer reviewed
Institute(s) Institute of Ecological Chemistry (IOEC)