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Reuter, S. ; Ilim, M.* ; Munch, J.-C. ; Andreux, F.* ; Scheunert, I.

A model for the formation and degradation of bound residues of the herbicide 14C-isoproturon in soil.

Chemosphere 39, 627-639 (1999)
DOI
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The humic monomer catechol was reacted with 14C-isoproturon and some of its metabolites, including 14C-4-isopropylaniline, in aqueous solution under a stream of oxygen. Only in the case of 14C-4-isopropylaniline, incorporation in oligomers, in fulvic acid-like polymers, and in humic acid-like polymers was observed. The main oligomer was identified by mass spectrometry as 4,5-bis-(4-isopropylphenylamino)-3,5-cyclohexadiene-1,2-dione. Oligomers and polymers containing bound 14C-4-isopropylaniline were subjected to biodegradation studies in a loamy agricultural soil during 55 days by quantifying 14CO2 evolved. In all cases, significant mineralization rates could be determined, which, however, were much smaller than those of free 14C-isoproturon and free 14C-4-isopropylaniline in the same soil.  
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Publication type Article: Journal article
Document type Scientific Article
Keywords isoproturon; phenylurea herbicide; 4-isopropylaniline; biodegradation; bound residues; humic substances; catechol; quinone
Language english
Publication Year 1999
HGF-reported in Year 0
ISSN (print) / ISBN 0045-6535
e-ISSN 1879-1298
Journal Chemosphere
Quellenangaben Volume: 39, Issue: 4, Pages: 627-639 Article Number: , Supplement: ,
Publisher Elsevier
Publishing Place Kidlington, Oxford
Reviewing status Peer reviewed
Erfassungsdatum 1999-12-31