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A model for the formation and degradation of bound residues of the herbicide 14C-isoproturon in soil.
Chemosphere 39, 627-639 (1999)
The humic monomer catechol was reacted with 14C-isoproturon and some of its metabolites, including 14C-4-isopropylaniline, in aqueous solution under a stream of oxygen. Only in the case of 14C-4-isopropylaniline, incorporation in oligomers, in fulvic acid-like polymers, and in humic acid-like polymers was observed. The main oligomer was identified by mass spectrometry as 4,5-bis-(4-isopropylphenylamino)-3,5-cyclohexadiene-1,2-dione. Oligomers and polymers containing bound 14C-4-isopropylaniline were subjected to biodegradation studies in a loamy agricultural soil during 55 days by quantifying 14CO2 evolved. In all cases, significant mineralization rates could be determined, which, however, were much smaller than those of free 14C-isoproturon and free 14C-4-isopropylaniline in the same soil.
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Publication type
Article: Journal article
Document type
Scientific Article
Keywords
isoproturon; phenylurea herbicide; 4-isopropylaniline; biodegradation; bound residues; humic substances; catechol; quinone
Language
english
Publication Year
1999
HGF-reported in Year
0
ISSN (print) / ISBN
0045-6535
e-ISSN
1879-1298
Journal
Chemosphere
Quellenangaben
Volume: 39,
Issue: 4,
Pages: 627-639
Publisher
Elsevier
Publishing Place
Kidlington, Oxford
Reviewing status
Peer reviewed
Institute(s)
Institute of Soil Ecology (IBOE)
Erfassungsdatum
1999-12-31