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Characterization of dissolved organic matter in full scale continuous stirred tank biogas reactors using ultrahigh resolution mass spectrometry: A qualitative overview.
Environ. Sci. Technol. 46, 12711-12719 (2012)
Dissolved organic matter (DOM) was characterized in eight full scale continuous stirred tank biogas reactors (CSTBR) using solid-phase extraction and electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FT-ICR-MS). An overview of the DOM molecular complexity in the samples from biogas reactors with conventional operational conditions and various substrate profiles is provided by assignments of unambiguous exact molecular formulas for each measured mass peak. Analysis of triplicate samples for each reactor demonstrated the reproducibility of the solid-phase extraction procedure and ESI-FT-ICR-MS which allowed precise evaluation of the DOM molecular differences among the different reactors. Cluster analysis on mass spectrometric data set showed that the biogas reactors treating sewage sludge had distinctly different DOM characteristics compared to the codigesters treating a combination of organic wastes. Furthermore, the samples from thermophilic and mesophilic codigesters had different DOM composition in terms of identified masses and corresponding intensities. Despite the differences, the results demonstrated that compositionally linked organic compounds comprising 28-59% of the total number of assigned formulas for the samples were shared in all the reactors. This suggested that the shared assigned formulas in studied CSTBRs might be related to common biochemical transformation in anaerobic digestion process and therefore, performance of the CSTBRs.
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Publication type
Article: Journal article
Document type
Scientific Article
Keywords
Water-treatment Plants ; Molecular Characterization ; Anaerobic-digestion ; Waste-water ; Black Carbon ; Spectra ; Electrospray ; Degradation ; Acids ; River
Language
english
Publication Year
2012
HGF-reported in Year
2013
ISSN (print) / ISBN
0013-936X
e-ISSN
1520-5851
Quellenangaben
Volume: 46,
Issue: 22,
Pages: 12711-12719
Publisher
ACS
Publishing Place
Washington, DC
Reviewing status
Peer reviewed
Institute(s)
Research Unit BioGeoChemistry and Analytics (BGC)
POF-Topic(s)
30202 - Environmental Health
Research field(s)
Environmental Sciences
PSP Element(s)
G-504800-001
PubMed ID
23110574
WOS ID
WOS:000311873500058
Scopus ID
84869464924
Erfassungsdatum
2013-03-07