PuSH - Publication Server of Helmholtz Zentrum München: Time-resolved analysis of the emission of Sidestream Smoke (SSS) from cigarettes during smoking by Photo Ionisation/Time-Of-Flight Mass Spectrometry (PI-TOFMS): Towards a better description of environmental tobacco smoke.

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Streibel, T. ; Mitschke, S. ; Adam, T. ; Zimmermann, R.

Time-resolved analysis of the emission of Sidestream Smoke (SSS) from cigarettes during smoking by Photo Ionisation/Time-Of-Flight Mass Spectrometry (PI-TOFMS): Towards a better description of environmental tobacco smoke.

Anal. Bioanal. Chem. 405, 7071-7082 (2013)

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Open Access Green as soon as Postprint is submitted to ZB.

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In this study, the chemical composition of sidestream smoke (SSS) emissions of cigarettes are characterised using a laser-based single-photon ionisation time-of-flight mass spectrometer. SSS is generated from various cigarette types (2R4F research cigarette; Burley, Oriental and Virginia single-tobacco-type cigarettes) smoked on a single-port smoking machine and collected using a so-called fishtail chimney device. Using this setup, a puff-resolved quantification of several SSS components was performed. Investigations of the dynamics of SSS emissions show that concentration profiles of various substances can be categorised into several groups, either depending on the occurrence of a puff or uninfluenced by the changes in the burning zone during puffing. The SSS emissions occurring directly after a puff strongly resemble the composition of mainstream smoke (MSS). In the smouldering phase, clear differences between MSS and SSS are observed. The changed chemical profiles of SSS and MSS might be also of importance on environmental tobacco smoke which is largely determined by SSS. Additionally, the chemical composition of the SSS is strongly affected by the tobacco type. Hence, the higher nitrogen content of Burley tobacco leads to the detection of increased amounts of nitrogen-containing substances in SSS.

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Publication type Article: Journal article

Document type Scientific Article

Corresponding Author

Keywords Sidestream cigarette smoke; Time-of-flight mass spectronomy; Photo ionisation; Laser Infrared-spectroscopy ; Electron-impact Ionization ; Mainstream Smoke ; Chemical-composition ; Complex-mixtures ; Passive Smoking ; Single Puff ; Chromatography ; Components ; Exposure

ISSN (print) / ISBN 1618-2642

e-ISSN 1618-2650

Journal Analytical and Bioanalytical Chemistry

Quellenangaben Volume: 405, Issue: 22, Pages: 7071-7082

Publisher Springer

Publishing Place Heidelberg

Non-patent literature Publications

Reviewing status Peer reviewed

Institute(s) Cooperation Group Comprehensive Molecular Analytics (CMA)