PuSH - Publication Server of Helmholtz Zentrum München

Export: TXT Text RIS Endnote (RIS) BIB BibTeX
Schilling, F.* ; Warner, L.R. ; Gershenzon, N.I.* ; Skinner, T.E.* ; Sattler, M. ; Glaser, S.J.*

Next-generation heteronuclear decoupling for high-field biomolecular NMR spectroscopy.

Angew. Chem.-Int. Edit. 53, 4475-4479 (2014)
DOI
Open Access Green as soon as Postprint is submitted to ZB.
Ultra-high-field NMR spectroscopy requires an increased bandwidth for heteronuclear decoupling, especially in biomolecular NMR applications. Composite pulse decoupling cannot provide sufficient bandwidth at practical power levels, and adiabatic pulse decoupling with sufficient bandwidth is compromised by sideband artifacts. A novel low-power, broadband heteronuclear decoupling pulse is presented that generates minimal, ultra-low sidebands. The pulse was derived using optimal control theory and represents a new generation of decoupling pulses free from the constraints of periodic and cyclic sequences. In comparison to currently available state-of-the-art methods this novel pulse provides greatly improved decoupling performance that satisfies the demands of high-field biomolecular NMR spectroscopy.
Impact Factor
Scopus SNIP
Web of Science
Times Cited
Scopus
Cited By
Altmetric
11.336
2.210
20
22
Tags
Annotations
Special Publikation
Hide on homepage

Edit extra information
Edit own tags
Private
Edit own annotation
Private
Hide on publication lists
on hompage
Mark as special
publikation
Publication type Article: Journal article
Document type Scientific Article
Keywords Decoupling Sidebands ; Nmr Spectroscopy ; Nucleic Acids ; Proteins ; Ultra-broadband Decoupling; Magnetic-resonance-spectroscopy; Optimal-control Design; Broad-band; Adiabatic Pulses; Resolution; Excitation; Inversion; Reconstruction; Acquisition; Calibration
Language english
Publication Year 2014
HGF-reported in Year 2014
ISSN (print) / ISBN 1433-7851
e-ISSN 1521-3773
Journal Angewandte Chemie - Internationale Edition
Quellenangaben Volume: 53, Issue: 17, Pages: 4475-4479 Article Number: , Supplement: ,
Publisher Wiley
Publishing Place Weinheim
Reviewing status Peer reviewed
Institute(s) Institute of Structural Biology (STB)
POF-Topic(s) 30203 - Molecular Targets and Therapies
Research field(s) Enabling and Novel Technologies
PSP Element(s) G-503000-001
DOI 10.1002/anie.201400178
WOS ID WOS:000334396800038
Scopus ID 84899449603
Scopus ID 84895777110
Erfassungsdatum 2014-03-28
[➜Report correction]