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Open Access Green as soon as Postprint is submitted to ZB.
Next-generation heteronuclear decoupling for high-field biomolecular NMR spectroscopy.
Angew. Chem.-Int. Edit. 53, 4475-4479 (2014)
Ultra-high-field NMR spectroscopy requires an increased bandwidth for heteronuclear decoupling, especially in biomolecular NMR applications. Composite pulse decoupling cannot provide sufficient bandwidth at practical power levels, and adiabatic pulse decoupling with sufficient bandwidth is compromised by sideband artifacts. A novel low-power, broadband heteronuclear decoupling pulse is presented that generates minimal, ultra-low sidebands. The pulse was derived using optimal control theory and represents a new generation of decoupling pulses free from the constraints of periodic and cyclic sequences. In comparison to currently available state-of-the-art methods this novel pulse provides greatly improved decoupling performance that satisfies the demands of high-field biomolecular NMR spectroscopy.
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Publication type
Article: Journal article
Document type
Scientific Article
Keywords
Decoupling Sidebands ; Nmr Spectroscopy ; Nucleic Acids ; Proteins ; Ultra-broadband Decoupling; Magnetic-resonance-spectroscopy; Optimal-control Design; Broad-band; Adiabatic Pulses; Resolution; Excitation; Inversion; Reconstruction; Acquisition; Calibration
ISSN (print) / ISBN
1433-7851
e-ISSN
1521-3773
Quellenangaben
Volume: 53,
Issue: 17,
Pages: 4475-4479
Publisher
Wiley
Publishing Place
Weinheim
Non-patent literature
Publications
Reviewing status
Peer reviewed
Institute(s)
Institute of Structural Biology (STB)