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Investigation, by single photon ionisation (SPI)-time-of-flight mass spectrometry (TOFMS), of the effect of different cigarette-lighting devices on the chemical composition of the first cigarette puff.
Anal. Bioanal. Chem. 387, 575-584 (2007)
Abstract Soft single-photon ionisation (SPI)–time-of-flight mass spectrometry (TOFMS) has been used to investigate the effect of different cigarette-lighting devices on the chemical composition of the mainstream smoke from the first cigarette puff. Lighting devices examined were a Borgwaldt electric lighter, a propane/butane gas lighter, a match, a candle, and the burning zone of another cigarette. To eliminate the effects of the different masses of tobacco burnt by use of the different lighting methods a normalisation procedure was performed which enabled investigation of changes in the chemical patterns of the resulting smoke. When another cigarette was used as the lighting device, elevated levels of ammonia and other nitrogen-containing substances were observed. These are high in the sidestream smoke of the cigarette used for lighting and would be drawn into the mainstream smoke of the cigarette being lit. In contrast, smoke from the cigarette lit by the electric lighter contained slightly higher normalised amounts of isoprene. Lighting the cigarette by use of a candle resulted in larger amounts of substances, e.g. benzene, which most probably originated from thermal decomposition of wax. The composition of the first puff of smoke obtained by use of the three lighting methods with open flames (gas lighter, match, and candle) was usually similar whereas the composition of the smoke produced by use of the electric lighter and the cigarette as the lighter were more unique. The chemical patterns generated by the different lighting devices could, however, be separated by principal-component analyses. Two additional test series were also studied. In the first the cigarette was lit with an electric lighter, then extinguished, the ash was cut off, and the cigarette was re-lit. In the second the cigarette was heated in an oven to 80 °C for 5 min before being lit. These treatments did not result in changes in the chemical composition compared with cigarettes lit in the ordinary way.
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Publication type
Article: Journal article
Document type
Scientific Article
Keywords
single photon ionisation; cigarette smoke; tobacco; principal-component analysis; first puff
Language
english
Publication Year
2007
HGF-reported in Year
2006
ISSN (print) / ISBN
1618-2642
e-ISSN
1618-2650
Quellenangaben
Volume: 387,
Issue: 2,
Pages: 575-584
Publisher
Springer
Publishing Place
Heidelberg
Reviewing status
Peer reviewed
Institute(s)
Institute of Ecological Chemistry (IOEC)
Cooperation Group Comprehensive Molecular Analytics (CMA)
Cooperation Group Comprehensive Molecular Analytics (CMA)
POF-Topic(s)
30202 - Environmental Health
30202 - Environmental Health
Research field(s)
Environmental Sciences
Environmental Sciences
PSP Element(s)
G-505100-002
G-504500-001
G-504500-001
PubMed ID
17171340
WOS ID
000243354400025
Scopus ID
33846071234
Erfassungsdatum
2006-12-14