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Open Access Green as soon as Postprint is submitted to ZB.
Surface catalyzed halogenation-dehalogenation reactions of aromatic bromine compounds adsorbed on fly ash.
Chemosphere 22, 1121-1129 (1991)
Brominated aromatic compounds like brominated benzenes, diphenylethers and dibenzodioxins adsorbed on the surface of fly ash from a municipal waste incininerator give mixed brominated/chlorinated und completely chlorinated aromatic compounds. These consecutive halogenation-dehalogenation reactions proceed by a nucleophilic mechanism, which is favoured by a high concentration of chloride on the fly ash. Results of kinetic and stereoselective behavior of these reactions will be discussed. The relevance of these results for PCDD/PCDF formation from bromine precursors in municipal waste incinerators will be discussed.
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Publication type
Article: Journal article
Document type
Scientific Article
ISSN (print) / ISBN
0045-6535
e-ISSN
1879-1298
Journal
Chemosphere
Quellenangaben
Volume: 22,
Issue: 12,
Pages: 1121-1129
Publisher
Elsevier
Publishing Place
Kidlington, Oxford
Non-patent literature
Publications
Reviewing status
Peer reviewed
Institute(s)
Institute of Ecological Chemistry (IOEC)