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Photoinduzierte hydroxylierungsreaktionen organischer chemikalien in natürlichen Gewässern - Nitrate als potentielle OH-radikalquellen -.

Chemosphere 11, 1041-1048 (1982)
DOI
Open Access Gold as soon as Publ. Version/Full Text is submitted to ZB.
Organic chemicals are concentrated in natural waters, where they undergo complex reactions under the influence of solar radiation and catalyzed by substances such as humic acid as well as nitrate and nitrite salts. Nitrates are present in high concentrations in natural waters (5 - 50 mg/l). The photolysis of the nitrate ion leads to the formation of OH-radicals. In this investigation the steady-state concentration of OH-radicals in different aquatic environments is estimated (∼ 5 · 10-16 mol/l). It depends on the amount of nitrate dissolved in the water. Under the conditions of this work the half life for a great number of organic chemicals lies in the range 80 - 400 hours (for the reaction with OH-radicals).
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Publication type Article: Journal article
Document type Scientific Article
Language german
Publication Year 1982
HGF-reported in Year 0
ISSN (print) / ISBN 0045-6535
e-ISSN 1879-1298
Journal Chemosphere
Quellenangaben Volume: 11, Issue: 10, Pages: 1041-1048 Article Number: , Supplement: ,
Publisher Elsevier
Publishing Place Kidlington, Oxford
Reviewing status Peer reviewed
Institute(s) Institute of Ecological Chemistry (IOEC)
Scopus ID 0020458994
Erfassungsdatum 1982-12-31