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Parlar, H.A. ; Hustert, K. ; Gaeb, S. ; Korte, F.

Isolation, identification, and chromatographic characterization of some chlorinated C10 hydrocarbons in technical chlordane.

J. Agric. Food Chem. 27, 278-283 (1979)
DOI
Open Access Green as soon as Postprint is submitted to ZB.
With the help of column chromatography, 3 new substances, 1-exo,4,5,7,8,8- hexachloro-3a,4,7,7a-tetrahydro-4,7-methanoindene 1-exo,2-exo,4,5,7,8,8- heptachloro-3a,4,7,7a-tetrahydro-4,7-methanoindane, and 1-exo,2-exo,4,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro-4,7-methanoindane, were isolated from technical chlordane and were identified by spectroscopic methods (mass spectrometry, infrared, and 1H NMR). These compounds could be synthesized by photochemical dechlorination of heptachlor and of α- (or cis-) chlordane in methanol. In addition, the mixture was investigated by capillary gas chromatography and by combined gas chromatography and mass spectrometry. The data obtained were used to characterize the composition of technical chlordane.
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Publication type Article: Journal article
Document type Scientific Article
ISSN (print) / ISBN 0021-8561
e-ISSN 1520-5118
Journal Journal of Agricultural and Food Chemistry
Quellenangaben Volume: 27, Issue: 2, Pages: 278-283 Article Number: , Supplement: ,
Publisher American Chemical Society (ACS)
Reviewing status Peer reviewed
Institute(s) Institute of Ecological Chemistry (IOEC)