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Gäb, S. ; Parlar, H.A. ; Korte, F.*

Structural elucidation of compound C. A chlordene isomer constituent of technical chlordane.

J. Agric. Food Chem. 25, 1224-1226 (1977)
DOI
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The constituent of technical chlordane designated compound C is an isomer of chlordene (C10H6Cl6). This isomer is formed via the rearrangement of isochlordene by the action of chlorine or free-radical initiating agents, such as Bz2O2/CCl4. By means of spectroscopic data (MS, IR, 1H NMR, and 13C NMR), it was shown that compound C does not possess the cyclodiene-type structure but corresponds to 3a,4,5,5a,5b,6-hexachloro-1a,2,3,3a,5a,5b-hexahydro-1,3-methano-1H-cyclobuta[gh] pentalene (III).
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Publication type Article: Journal article
Document type Scientific Article
Corresponding Author
ISSN (print) / ISBN 0021-8561
e-ISSN 1520-5118
Quellenangaben Volume: 25, Issue: 5, Pages: 1224-1226 Article Number: , Supplement: ,
Publisher American Chemical Society (ACS)
Non-patent literature Publications
Reviewing status Peer reviewed
Institute(s) Institute of Ecological Chemistry (IOEC)