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Structural elucidation of compound C. A chlordene isomer constituent of technical chlordane.
J. Agric. Food Chem. 25, 1224-1226 (1977)
The constituent of technical chlordane designated compound C is an isomer of chlordene (C10H6Cl6). This isomer is formed via the rearrangement of isochlordene by the action of chlorine or free-radical initiating agents, such as Bz2O2/CCl4. By means of spectroscopic data (MS, IR, 1H NMR, and 13C NMR), it was shown that compound C does not possess the cyclodiene-type structure but corresponds to 3a,4,5,5a,5b,6-hexachloro-1a,2,3,3a,5a,5b-hexahydro-1,3-methano-1H-cyclobuta[gh] pentalene (III).
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Publication type
Article: Journal article
Document type
Scientific Article
ISSN (print) / ISBN
0021-8561
e-ISSN
1520-5118
Quellenangaben
Volume: 25,
Issue: 5,
Pages: 1224-1226
Publisher
American Chemical Society (ACS)
Reviewing status
Peer reviewed
Institute(s)
Institute of Ecological Chemistry (IOEC)