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Isolation and identification of three unreported photodieldrin-14C metabolites in soil.
J. Agric. Food Chem. 23, 873-876 (1975)
Fifteen months after application of photodieldrin14C to soil (5 ppm of dry weight) in the open air, the following conversion products were identified by TLC, GLC, and mass spectrometry: the bridged isomer of dihydrochlordene dicarboxylic acid (1,7,8,exo-9,10,10-hexachlorotetracyclo[5.2.1.02,6.0 4,8]decane-3,5-exo,exo-dicarboxylic acid), amounting to about 0.5% of recovered radio-activity, a methoxylated derivative of this acid, amounting to about 0.5% of recovered radioactivity, and a bridged isomer of trans-4,5-dihydroxy-4,5-dihydroaldrin (3,exo-4,5,6,6,7-hexachloro-11,12-trans-dihydroxypentacyclo[6.4.0.0 2,10.03,7.05,9]dodecane), amounting to about 1% of recovered radioactivity.
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Publication type
Article: Journal article
Document type
Scientific Article
ISSN (print) / ISBN
0021-8561
e-ISSN
1520-5118
Quellenangaben
Volume: 23,
Issue: 5,
Pages: 873-876
Publisher
American Chemical Society (ACS)
Reviewing status
Peer reviewed
Institute(s)
Institute of Ecological Chemistry (IOEC)