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Open Access Green as soon as Postprint is submitted to ZB.
New photosynthesis-like system for the light-induced reduction of water to molecular hydrogen.
Angew. Chem.-Int. Edit. 26, 241-243 (1987)
Two zinc porphyrinate-modified Pt electrodes form the essential part of a very promising solar energy conversion system in which ultimately water is reduced to hydrogen. The Na//2 salt of ethylenediaminetetraacetic acid is employed as sacrificial electron donor; methyl viologen functions as electron transfer agent and platinized TiO//2 as reduction catalyst. Decisive is that the anode is coated with an n-semiconducting porphyrinate (zinc 5-(4-pyridyl)-10,15,20-tritolylporphyrinate) and the cathode with a p-semiconducting porphyrinate (zinc 5,10,15,20-tetra(4-pyridyl)porphyrinate).
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Publication type
Article: Journal article
Document type
Scientific Article
ISSN (print) / ISBN
1433-7851
e-ISSN
1521-3773
Quellenangaben
Volume: 26,
Issue: 3,
Pages: 241-243
Publisher
Wiley
Publishing Place
Weinheim
Non-patent literature
Publications
Reviewing status
Peer reviewed
Institute(s)
Institute of Ecological Chemistry (IOEC)