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Open Access Green as soon as Postprint is submitted to ZB.
Synthese und reaktionen von symmetrisch substituierten s-Triazinen unter hohem druck. Hochdruckreaktionen, 8. Mitteilung.
Tetrahedron 31, 619-623 (1975)
Two extensive mechanisms are proposed for cyclotrimerization of nitriles to s-triazines under high pressure. The availability of these mechanisms is proven by synthesis of some new symmetrically substituted s-triazines; simultaneously, however, their limits are demonstrated. Furthermore, there were found rearrangement and cyclic degradation reactions as reaction possibilities for s-triazines under high pressure. Both reactions are based on an equilibrium in alcohol between symmetrically substituted s-triazine and iminoether.
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Publication type
Article: Journal article
Document type
Scientific Article
ISSN (print) / ISBN
0040-4020
e-ISSN
1464-5416
Journal
Tetrahedron
Quellenangaben
Volume: 31,
Issue: 6,
Pages: 619-623
Publisher
Elsevier
Non-patent literature
Publications
Reviewing status
Peer reviewed
Institute(s)
Institute of Ecological Chemistry (IOEC)