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Gäb, S. ; Turner, W.V.

1,1-Dichloroethyl hydroperoxide and 1,1-dichloroethyl peroxide ion as intermediates in the ozonolysis of 2,3-dichloro-2-butene.

J. Org. Chem. 49, 2711-2714 (1984)

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Open Access Green as soon as Postprint is submitted to ZB.

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On the basis of its spectroscopic and chemical properties, an unstable intermediate previously detected in the ozonolysis of trans-2,3-dichloro-2-butene (1) in inert solvents is reformulated as 1,1-dichloroethyl hydroperoxide (5). Ozonolysis of 1 in ethyl formate saturated with anhydrous HCl leads to high yields of this intermediate. 1,1-Dichloroethyl peroxide ion (10), rather than 5, is believed to be the precursor of acetyl 1,1-dichloroethyl peroxide (8), which is produced in higher yield on ozonolysis of 1 in the presence of tetraalkylammonium chloride.

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Publication type Article: Journal article

Document type Scientific Article

Corresponding Author

ISSN (print) / ISBN 0022-3263

e-ISSN 1520-6904

Journal Journal of Organic Chemistry, The

Quellenangaben Volume: 49, Issue: 15, Pages: 2711-2714

Publisher American Chemical Society (ACS)

Non-patent literature Publications

Reviewing status Peer reviewed

Institute(s) Institute of Ecological Chemistry (IOEC)