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Gas phase ion-molecule reactions of inorganic compounds in FT-ICR-MS.
In: Fundamentals and Applications of Fourier Transform Mass Spectrometry. 2019. 569-591
Reactions between ions and
reactive neutrals in the gas phase at near thermal energy conditions are
feasible, provided that means exist to trap ions for a couple of seconds for collisions between ions and reactive neutrals to occur. The ion cyclotron resonance
(ICR) technique provides an excellent environment for such gas phase
ion-molecule reactions to take place, giving also the opportunity to
correlate both reactant and product ions and to determine sum formulae
with ultra-high resolution. Moreover, ICR can also enable structure elucidation by several techniques like collision induced dissociation
(CID) experiments. Acceleration of some reactive ions can also induce
endothermic ion-molecule reactions to occur. The authors give a
systematic overview of gas phase ion chemistry of non-metal main group elements, covering a wide spectrum of reactions, as well as their rate constant determinations and thermodynamic ion energetics.
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Publication type
Article: Edited volume or book chapter
Book Volume Title
Fundamentals and Applications of Fourier Transform Mass Spectrometry
Quellenangaben
Pages: 569-591
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Research Unit BioGeoChemistry and Analytics (BGC)