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Gáspár, A. ; Schmitt-Kopplin, P.

Identification of polyborate ions in aqueous solution by electrospray ionisation Fourier transform ion cyclotron resonance mass spectrometry.

Eur. J. Mass Spectrom. 16, 237-242 (2010)

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Open Access Green as soon as Postprint is submitted to ZB.

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Ultra-high-resolution mass spectrometry was used to investigate polyborate species in aqueous solution. The mass spectrum of boric acid revealed clusters of polyborate ions. Constituents with up to 19 B atoms were assigned and 15 species and their relationship were investigated in depth with collision-induced fragmentation. Based on the observed fragments, we proposed herein a potential fragmentation pathway for the observed polyborate molecules.

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Publication type Article: Journal article

Document type Scientific Article

Corresponding Author

Keywords boron; polyborate; borate; boric acid; mass spectrometry; FT-ICR /MS; collusion-induced fragmentation; electrospray ionization

ISSN (print) / ISBN 1469-0667

e-ISSN 1751-6838

Journal European Journal of Mass Spectrometry

Quellenangaben Volume: 16, Issue: 2, Pages: 237-242

Publisher IM Publications

Non-patent literature Publications

Reviewing status Peer reviewed

Institute(s) Institute of Ecological Chemistry (IOEC)