PuSH - Publication Server of Helmholtz Zentrum München: Advanced mass spectrometric techniques for the comprehensive study of synthesized silicon-based silyl organic compounds : Identifying fragmentation pathways and characterization.

Navigation

Home

Deutsch

Research

Advanced Search

Browse by ...

... Journal

... Publication Type

... Research Data

... Publication Year

Publication overview

Support & Contact

Contact persons

Help

Data protection

Rogowska, A.* ; Szultka-Młyńska, M.* ; Kanawati, B. ; Pomastowski, P.* ; Arendowski, A.* ; Gołębiowski, A.* ; Schmitt-Kopplin, P. ; Fordymacka, M.* ; Sukiennik, J.* ; Krzywik, J.* ; Buszewski, B.*

Advanced mass spectrometric techniques for the comprehensive study of synthesized silicon-based silyl organic compounds : Identifying fragmentation pathways and characterization.

Materials 16:17 (2023)

Publ. Version/Full Text

DOI

PMC

Abstract
Metrics
Extra information

The primary objective of this study was to synthesize and characterize novel silicon-based silyl organic compounds in order to gain a deeper understanding of their potential applications and interactions with other compounds. Four new artificial silyl organic compounds were successfully synthesized: 1-O-(Trimethylsilyl)-2,3,4,6-tetra-O-acetyl-β-d-glucopyranose (compound 1), 1-[(1,1-dimethylehtyl)diphenylsilyl]-1H-indole (compound 2), O-tert-butyldiphenylsilyl-(3-hydroxypropyl)oleate (compound 3), and 1-O-tert-Butyldiphenylsilyl-myo-inositol (compound 4). To thoroughly characterize these synthesized compounds, a combination of advanced mass spectrometric techniques was employed, including nanoparticle-assisted laser desorption/ionization mass spectrometry (NALDI-MS), Fourier-transform ion cyclotron resonance mass spectrometry (FT-ICR-MS), and triple quadrupole electrospray tandem mass spectrometry (QqQ ESI-MS/MS). These analytical methods enabled the accurate identification and characterization of the synthesized silyl organic compounds, providing valuable insights into their properties and potential applications. Furthermore, the electrospray ionization-Fourier transform ion cyclotron resonance-tandem mass spectrometry (ESI-FT-ICR-MS/MS) technique facilitated the proposal of fragmentation pathways for the ionized silyl organic compounds, contributing to a more comprehensive understanding of their behavior during mass spectrometric analysis. These findings suggest that mass spectrometric techniques offer a highly effective means of investigating and characterizing naturally occurring silicon-based silyl organic compounds, with potential implications for advancing research in various fields and applications in different industries.

Altmetric

Additional Metrics?

[➜Log in]

Edit extra informations Login

Publication type Article: Journal article

Document type Scientific Article

Corresponding Author

Keywords Fragmentation Pathway ; Mass Spectrometry ; Organic Synthesis ; Silicon-based Silyl Organic Compounds; Association; Plants

ISSN (print) / ISBN 1996-1944

Journal Materials

Quellenangaben Volume: 16, Issue: 9, Article Number: 17

Publisher MDPI

Publishing Place Basel

Non-patent literature Publications

Reviewing status Peer reviewed

Institute(s) Research Unit Analytical BioGeoChemistry (BGC)

Grants National Science Centre of Poland (Krakow, Poland)