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Open Access Green as soon as Postprint is submitted to ZB.
Thermal degradation of wood treated with creosote.
J. Anal. Appl. Pyrol. 57, 15-36 (2001)
The results of investigations on the thermal behaviour of wood, wood treated with creosote, and of creosote are reported. Thermal analysis coupled with ion impact mass spectrometry as well as thermolysis in the modified Bayer-ICI-Shell combustion apparatus (BIS) were applied. The emission products from the BIS-apparatus were analysed qualitatively and quantitatively by gas chromatography coupled with a mass selective detector (GC/MSD). It is shown, that the degradation of creosote and wood treated with creosote is starting with a drying process of the wood around 75 degreesC, followed by evaporation of the creosote compounds between 180 and 400 degreesC. Wood itself is decomposed in an anaerobic process between 300 and 340 degreesC, followed by an oxidative process around 400 degreesC. The oxidative decomposition and mineralisation of creosote takes place between 400 and 600 degreesC with a maximum at 540 degreesC.
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Publication type
Article: Journal article
Document type
Scientific Article
Keywords
Wood; Creosote; Combustion; TA-MS; Pyrolysis
Language
english
Publication Year
2001
HGF-reported in Year
0
ISSN (print) / ISBN
0165-2370
e-ISSN
0165-2370
Quellenangaben
Volume: 57 ,
Issue: 1,
Pages: 15-36
Publisher
Elsevier
Reviewing status
Peer reviewed
Institute(s)
Institute of Ecological Chemistry (IOEC)
PSP Element(s)
G-505100-003
Scopus ID
0035156689
Erfassungsdatum
2001-12-31