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Chloroaromatic formation in incineration processes.
Sci. Total Environ. 269, 1-24 (2001)
The high-temperature reactions of chlorinated hydrocarbons are reviewed with a primary focus on the gas-phase molecular growth chemistry and elementary reaction mechanisms leading to the formation of chlorinated benzenes and chlorinated polycyclic aromatic hydrocarbons. Recent heterogeneous mechanistic studies of the chlorination and condensation of aliphatic hydrocarbons at lower temperatures are also summarized. Copper(II) valent species play an important role as catalyst and reagent. The main thermal pathways for chlorinated dibenzodioxins and furans have been deduced by these laboratory experiments, which try to model the complex reality of the post-incineration zone of municipal and hazardous waste incinerators.
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Publication type
Article: Journal article
Document type
Review
Keywords
Chlorinated hydrocarbons; Pyrolysis; Molecular growth; Chlorinated polycyclic aromatic hydrocarbons; Polychlorinated dibenzo-p-dioxins; Furan
Language
english
Publication Year
2001
HGF-reported in Year
0
ISSN (print) / ISBN
0048-9697
e-ISSN
1879-1026
Quellenangaben
Volume: 269 ,
Issue: 1-3,
Pages: 1-24
Publisher
Elsevier
Reviewing status
Peer reviewed
Institute(s)
Institute of Ecological Chemistry (IOEC)
PSP Element(s)
G-505100-003
Scopus ID
0035953102
PubMed ID
11305331
Erfassungsdatum
2001-12-31