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PuSH - Publication Server of Helmholtz Zentrum München: Synthese und reaktionen von symmetrisch substituierten s-Triazinen unter hohem druck. Hochdruckreaktionen, 8. Mitteilung.
Two extensive mechanisms are proposed for cyclotrimerization of nitriles to s-triazines under high pressure. The availability of these mechanisms is proven by synthesis of some new symmetrically substituted s-triazines; simultaneously, however, their limits are demonstrated. Furthermore, there were found rearrangement and cyclic degradation reactions as reaction possibilities for s-triazines under high pressure. Both reactions are based on an equilibrium in alcohol between symmetrically substituted s-triazine and iminoether.