PuSH - Publikationsserver des Helmholtz Zentrums München

Export: TXT Text RIS Endnote (RIS) BIB BibTeX
Schilling, F.* ; Warner, L.R. ; Gershenzon, N.I.* ; Skinner, T.E.* ; Sattler, M. ; Glaser, S.J.*

Next-generation heteronuclear decoupling for high-field biomolecular NMR spectroscopy.

Angew. Chem.-Int. Edit. 53, 4475-4479 (2014)
DOI
Open Access Green möglich sobald Postprint bei der ZB eingereicht worden ist.
Ultra-high-field NMR spectroscopy requires an increased bandwidth for heteronuclear decoupling, especially in biomolecular NMR applications. Composite pulse decoupling cannot provide sufficient bandwidth at practical power levels, and adiabatic pulse decoupling with sufficient bandwidth is compromised by sideband artifacts. A novel low-power, broadband heteronuclear decoupling pulse is presented that generates minimal, ultra-low sidebands. The pulse was derived using optimal control theory and represents a new generation of decoupling pulses free from the constraints of periodic and cyclic sequences. In comparison to currently available state-of-the-art methods this novel pulse provides greatly improved decoupling performance that satisfies the demands of high-field biomolecular NMR spectroscopy.
Impact Factor
Scopus SNIP
Web of Science
Times Cited
Scopus
Cited By
Altmetric
11.336
2.210
20
22
Tags
Anmerkungen
Besondere Publikation
Auf Hompepage verbergern

Zusatzinfos bearbeiten
Eigene Tags bearbeiten
Privat
Eigene Anmerkung bearbeiten
Privat
Auf Publikationslisten für
Homepage nicht anzeigen
Als besondere Publikation
markieren
Publikationstyp Artikel: Journalartikel
Dokumenttyp Wissenschaftlicher Artikel
Schlagwörter Decoupling Sidebands ; Nmr Spectroscopy ; Nucleic Acids ; Proteins ; Ultra-broadband Decoupling; Magnetic-resonance-spectroscopy; Optimal-control Design; Broad-band; Adiabatic Pulses; Resolution; Excitation; Inversion; Reconstruction; Acquisition; Calibration
Sprache englisch
Veröffentlichungsjahr 2014
HGF-Berichtsjahr 2014
ISSN (print) / ISBN 1433-7851
e-ISSN 1521-3773
Zeitschrift Angewandte Chemie - Internationale Edition
Quellenangaben Band: 53, Heft: 17, Seiten: 4475-4479 Artikelnummer: , Supplement: ,
Verlag Wiley
Verlagsort Weinheim
Begutachtungsstatus Peer reviewed
Institut(e) Institute of Structural Biology (STB)
POF Topic(s) 30203 - Molecular Targets and Therapies
Forschungsfeld(er) Enabling and Novel Technologies
PSP-Element(e) G-503000-001
DOI 10.1002/anie.201400178
WOS ID WOS:000334396800038
Scopus ID 84899449603
Scopus ID 84895777110
Erfassungsdatum 2014-03-28
[➜Korrektur melden]