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New photosynthesis-like system for the light-induced reduction of water to molecular hydrogen.
Angew. Chem.-Int. Edit. 26, 241-243 (1987)
Two zinc porphyrinate-modified Pt electrodes form the essential part of a very promising solar energy conversion system in which ultimately water is reduced to hydrogen. The Na//2 salt of ethylenediaminetetraacetic acid is employed as sacrificial electron donor; methyl viologen functions as electron transfer agent and platinized TiO//2 as reduction catalyst. Decisive is that the anode is coated with an n-semiconducting porphyrinate (zinc 5-(4-pyridyl)-10,15,20-tritolylporphyrinate) and the cathode with a p-semiconducting porphyrinate (zinc 5,10,15,20-tetra(4-pyridyl)porphyrinate).
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Anmerkungen
Besondere Publikation
Auf Hompepage verbergern
Publikationstyp
Artikel: Journalartikel
Dokumenttyp
Wissenschaftlicher Artikel
Sprache
englisch
Veröffentlichungsjahr
1987
HGF-Berichtsjahr
0
ISSN (print) / ISBN
1433-7851
e-ISSN
1521-3773
Zeitschrift
Angewandte Chemie - Internationale Edition
Quellenangaben
Band: 26,
Heft: 3,
Seiten: 241-243
Verlag
Wiley
Verlagsort
Weinheim
Begutachtungsstatus
Peer reviewed
Institut(e)
Institute of Ecological Chemistry (IOEC)
Scopus ID
0023312593
Erfassungsdatum
1987-12-31