Open Access Green möglich sobald Postprint bei der ZB eingereicht worden ist.
Method for dead time determination in reversed-phase capillary electrochromatography with methacrylate-based stationary phases.
Chromatographia 58, 803-806 (2003)
A method for dead time determination in reversed-phase capillary electrochromatography (RP-CEC) with methacrylate-based monolithic stationary phases has been presented based on homologue series method. The dead times measured with homologue series method and thiourea, a commonly used electroosmotic flow (EOF) marker are compared under various conditions, such as the type and the concentration of organic modifier, ionic strength, and applied voltage. Results show that the former one is larger than the latter one. Under high ionic strength and low applied voltage, EOF velocity measured by thiourea is close to that determined by homologue series method.
Impact Factor
Scopus SNIP
Web of Science
Times Cited
Times Cited
Altmetric
1.230
0.000
4
Anmerkungen
Besondere Publikation
Auf Hompepage verbergern
Publikationstyp
Artikel: Journalartikel
Dokumenttyp
Wissenschaftlicher Artikel
Schlagwörter
capillary electrochromatography; electroosmotic flow; polymer monolithic column; Homologue series; dead time
Sprache
englisch
Veröffentlichungsjahr
2003
HGF-Berichtsjahr
0
ISSN (print) / ISBN
0009-5893
e-ISSN
1612-1112
Zeitschrift
Chromatographia
Quellenangaben
Band: 58,
Heft: 11,
Seiten: 803-806
Verlag
Springer
Begutachtungsstatus
Peer reviewed
Institut(e)
Institute of Ecological Chemistry (IOEC)
PSP-Element(e)
G-505100-007
Erfassungsdatum
2004-05-10