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Chloroaromatic formation in incineration processes.
Sci. Total Environ. 269, 1-24 (2001)
The high-temperature reactions of chlorinated hydrocarbons are reviewed with a primary focus on the gas-phase molecular growth chemistry and elementary reaction mechanisms leading to the formation of chlorinated benzenes and chlorinated polycyclic aromatic hydrocarbons. Recent heterogeneous mechanistic studies of the chlorination and condensation of aliphatic hydrocarbons at lower temperatures are also summarized. Copper(II) valent species play an important role as catalyst and reagent. The main thermal pathways for chlorinated dibenzodioxins and furans have been deduced by these laboratory experiments, which try to model the complex reality of the post-incineration zone of municipal and hazardous waste incinerators.
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1.252
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Anmerkungen
Besondere Publikation
Auf Hompepage verbergern
Publikationstyp
Artikel: Journalartikel
Dokumenttyp
Review
Schlagwörter
Chlorinated hydrocarbons; Pyrolysis; Molecular growth; Chlorinated polycyclic aromatic hydrocarbons; Polychlorinated dibenzo-p-dioxins; Furan
Sprache
englisch
Veröffentlichungsjahr
2001
HGF-Berichtsjahr
0
ISSN (print) / ISBN
0048-9697
e-ISSN
1879-1026
Zeitschrift
Science of the Total Environment, The
Quellenangaben
Band: 269 ,
Heft: 1-3,
Seiten: 1-24
Verlag
Elsevier
Begutachtungsstatus
Peer reviewed
Institut(e)
Institute of Ecological Chemistry (IOEC)
PSP-Element(e)
G-505100-003
Scopus ID
0035953102
PubMed ID
11305331
Erfassungsdatum
2001-12-31