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Temoka, P.* ; Pfister, G. ; Henkelmann, B. ; Schramm, K.-W.

Adapting current model with field data of related performance reference compounds in passive samplers to accurately monitor hydrophobic organic compounds in aqueous media.

Environ. Monit. Assess. 189:543 (2017)

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	Open Access Green

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Performance reference compounds (PRCs) are neutral organic compounds, introduced in a passive sampler prior deployment for the assessment of in situ sampling rate. In this study, evaluation of in situ sampling rates of 16 (13)C-PAH-PRCs with moderate and high hydrophobicity was established to provide an overall correction factor for variations in virtual organism (VO) uptake rates of the analytes of interest. In situ sampling rate was compared to an empirical model during sampling campaign in 2011 with VO in 12 different sites along the Three Gorges Reservoir (TGR) in China. A discrepancy was observed for high hydrophobic compounds with log K ow ranging from 5.18 to 6.63 where ΣPAH concentration in TGR from Huckins model (305,624 pg/L) was resulted to be roughly 2-fold higher than the alternative procedure (182,292 pg/L). A relationship between in situ sampling rates of the 16 (13)C-PAH-PRCs (Rs, PRC ) and log K ow was set up to allow then calculation of analyte sampling rate Rs analyte (N) of various organic pollutants with log K ow ≤ 6.63.

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Publication type Article: Journal article

Document type Scientific Article

Corresponding Author

Keywords Partition Coefficient ; Performance Reference Compounds ; Polycyclic Aromatic Hydrocarbons ; Sampling Rate ; Three Gorges Reservoir ; Virtual Organism; Semipermeable-membrane Devices; Polycyclic Aromatic-hydrocarbons; 3 Gorges Reservoir; Uptake Kinetics; Sampling Rates; Organochlorine Pesticides; Yangtze-river; Mass Fluxes; Water; Calibration

ISSN (print) / ISBN 0167-6369

e-ISSN 1573-2959

Journal Environmental Monitoring and Assessment

Quellenangaben Volume: 189, Issue: 11, Article Number: 543

Publisher Springer

Publishing Place Dordrecht

Non-patent literature Publications

Reviewing status Peer reviewed

Institute(s) PPM-MEX-Molecular EXposomics (MEX)