Gawlitta, N. ; Orasche, J. ; Geldenhuys, G.L.* ; Jakobi, G. ; Wattrus, M.* ; Jennerwein, M.* ; Michalke, B. ; Gröger, T.M. ; Forbes, P.* ; Zimmermann, R.
A study on the chemical profile and the derived health effects of heavy-duty machinery aerosol with a focus on the impact of alternative fuels.
Air qual. atoms. health 16, 535-551 (2022)
The combustion of petroleum-based fossil fuels is associated with a high environmental burden. Several alternative fuels, including synthetic fuels (e.g., gas-to-liquid, GTL) and biofuels (e.g., rapeseed methyl ester, RME) have been studied in the last few years. While the advantages for the environment (sustainability of biofuels) are well known, research on the resulting health effects from combustion aerosols of these alternative fuels is still scarce. Consequently, we investigated the chemical combustion profile from three distinct fuel types, including a petroleum-based fossil fuel (B0) and two alternative fuels (GTL, RME) under real exposure conditions. We sampled particulate matter (PM2.5, PM0.25) and the gas phase from heavy-duty machinery and evaluated the general pattern of volatile and semi-volatile organic compounds, elemental and organic carbon as well as a range of transition metals in the size segregated PM and/or gas phase. The use of comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry enabled us to classify distinct methylated PAHs in the PM samples and its high abundance, especially in the fine fraction of PM. We found that (methylated) PAHs were highly abundant in the PM of B0 compared to GTL and RME. Highest concentrations of targeted aromatic species in the gas phase were released from B0. In summary, we demonstrated that GTL and RME combustion released lower amounts of chemical compounds related to adverse health effects, thus, the substitution of petroleum-based fuels could improve air quality for human and the environment.
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Publication type
Article: Journal article
Document type
Scientific Article
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Keywords
(methylated) Pahs ; Alternative Fuels ; Combustion Aerosol ; Health Effects ; Ultrafine Particulate Matter; Polycyclic Aromatic-hydrocarbons; Size Distribution; Diesel-engine; Physicochemical Properties; Biodiesel; Emissions; Pahs; Combustion; Catalysts; Exhaust
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Language
english
Publication Year
2022
Prepublished in Year
0
HGF-reported in Year
2022
ISSN (print) / ISBN
1873-9318
e-ISSN
1873-9326
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Quellenangaben
Volume: 16,
Issue: 3,
Pages: 535-551
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Springer
Publishing Place
Dordrecht
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Reviewing status
Peer reviewed
POF-Topic(s)
30202 - Environmental Health
Research field(s)
Environmental Sciences
PSP Element(s)
G-504500-001
G-504800-002
Grants
German Federal Ministry of Education and Research (BMBF)
National Research Foundation of South Africa (NRF)
University of Pretoria
Projekt DEAL
Copyright
Erfassungsdatum
2023-01-11